Source Rock Evaluation and Lateral Changes in Thermal Maturity of the Sargelu Formation (Middle Jurassic) in Kurdistan Region-Northern Iraq
DOI:
https://doi.org/10.25079/ukhjse.v2n1y2018.pp7-17Keywords:
Biomarkers, Kurdistan, Rock-Eval, Sargelu Formation, Thermal MaturityAbstract
In this study, source rock characteristics and lateral changes in thermal maturity of the Sargelu Formation (Middle Jurassic) in three outcrops were studied. The formation’s outcrops can be found in the High Folded, and Imbricated Zones of Iraqi Tectonic Division. In order to achieve the main goals of this study, the Gas chromatography mass spectrometry (GC-MS) and Rock-Eval pyrolysis were performed on the organic matter (OM) of the Sargelu sediments. Pristane/Phytane ratios for analyzed samples indicate reducing conditions (anoxic) during sedimentation. Moreover, based on C29/C30 hopanes ratios the sediments of the Sargelu Formation associated with clay- rich source rock. Biomarker thermal maturity parameters display that all samples are thermally in Oil Window at least. The biomarker findings reveal that the samples of Walasimt and Barsarin are seem more mature than Banik section.
The values for TOC% of the Sargelu Formation may show Excellent, Very Good, and Poor quality source rock. The Pyrolysis executed for studied samples revealed the kerogen in Banik section belongs to Types II and III (Probably Oil/Gas- prone), while Barsarin and Walasimt sections obtained Types III-IV Kerogen (Gas- prone). Pyrolysis parameters suggested Early Mature Stage in Banik, While Overmature in Barsarin and Walasimt. The data also shows that organic matter of the Sargelu Formation in Banik section is in Oil Widow, while in Barsarin and Walasimt is in Gas Window.
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References
Abdula, R. A. (2014). Hydrocarbon potential of Sargelu formation and oil-source correlation, Iraqi Kurdistan. Arabian Journal of Geoscience, 8(8), 5845-5868.
Al-Barzanji, S. T. M. (1989). Facies Analysis for Muhaiwir Formation-W. Iraq: M.S. Thesis (Unpublished), Science College, University of Baghdad, Baghdad, Iraq. p. 86.
Al-Sayyab, A., Al-Ansari, N., Al-Rawi, D., Al-Omari, F., Al-Shaikh, Z. & Al-Jassim, J. (1982). Geology of Iraq. Mosul: University of Al- Mosul. p. 280.
Aqrawi, A. A. M., Goff, J. C. Horbury, A. D. & Sadooni, F. N. I. (2010). The Petroleum Geology of Iraq: Beaconsfield. United Kingdom: Scientific Press Ltd. p. 424.
Balaky, S. M. H. (2004). Stratigraphy and Sedimentology of Sargelu Formation (Middle Jurassic) in Selected Sections in Erbil and Duhuk Governorates–Iraqi Kurdistan. M.S. Thesis (Unpublished), Science College, University of Salahaddin, Erbil, Iraq. p. 109.
Bellen, R. C., Van Dunnigton, H. V., Wetzel, R. & Morton, D. M. (1959). Lexique Stratigraphique International. Vol. III. Paris: Asie, Fasc., 10a Iraq. p. 333.
Brooks, J. D., Gould, K. & Smith, J. W. (1969). Isoprenoid hydrocarbons in coal and petroleum. Nature, 222, 257-259.
Buday, T. (1980). The Regional Geology of Iraq. Stratigraphy and Paleogeography. Vol. 1. Iraq: Dar Al-Kutub Publication University of Mosul. p. 445.
Beydoun, Z. R. (1993). Evolution of the northeastern Arabian plate margin and shelf: Hydrocarbon habitat and conceptual future potential. Revue de L’Institut Francais du Petrole, 48, 311-245.
Darvichzada, A. (1992). Geology of Iran. Tehran: G.S. of Iran. p. 901.
Dercourt, J., Zonenshain, L. P., Ricou, L. E., Kazmin, V. G., Le Pichon, X., Knipper, A. L., Grandjacquet, C., Sbortshikov, I. M., Geyssant, J., Lepvrier, C., Pechersky, D. H., Boulin, J., Sibuet, J. C., Savostin, L. A., Sorokhtin, O., Westphal, M., Bazhenov, M. L., Lauer, J. P. & Biju-Duval, B. (1986). Geological evolution of the Tethys belt from the Atlantic to the Pamir since the Lias, In: Aubouin, J., Le Pichon, X. & Monin, S., editors. Evolution of the Tethys. Vol. 123. Amsterdam: Tectonophysics. pp. 241-315.
Diatmar, V. & Others. (1971). Geological Conditions and Hydrocarbon Prospects of the Republic of Iraq (Northern and Central Parts). Techno Export Report. Baghdad: INOC Library.
Dunnington, H. V. (1958). Generation, migration, accumulation, and dissipation of oil in Northern Iraq. In: Weeks, L.G., editor. Habitat of Oil, a Symposium, AAPG Bulletin. p. 1194-1251.
Hunt, J. M. (1996). Petroleum Geochemistry and Geology. 2nd ed. San Francisco: W.H. Freeman. p. 707.
Jassim, S. Z. & Buday, T. (2006). Late Toarcian-Early Tithonian (Mid- Late Jurassic) Megasequence AP7, Chapter 10. In: Jassim, S. Z. & Goff, J. C., editors. Geology of Iraq. 1st ed. Brno, Czech Republic: Prague and Moravian Museum. pp. 117-123.
Jassim, S. Z. & Al-Gailani, M. (2006). Hydrocarbons, Chapter 18. In: Jassim, S. Z. & Goff, J. C., editors. Geology of Iraq. 1st ed. Brno, Czech Republic: Prague and Moravian Museum. pp. 232-250.
Jassim, S. Z. & Karim, S. A. (1984). Final Report on Regional Geology Survey of Iraq: Paleogeography. Vol. 4. Baghdad, Iraq: State Organization for Mineral. p. 69.
Katz, B. J. (1983). Limitations of Rock–Eval‘ pyrolysis for typing organic matter Org. Geochem, 4, 195-199.
Marouf, N. Z. (1999). Dynamic Evolution of the Sedimentary Basins in Northern Iraq and Hydrocarbon Formation, Migration and Entrapment. Ph.D. Thesis (Unpub.), University of Baghdad. p. 236.
Murris, R. J. (1980). Middle East–stratigraphic evolution and oil habitat. AAPG Bulletin, 64(5), 597-618.
Numan, N. M. S. (1997). A plate tectonic scenario for the Phanerozoic succession in Iraq. Iraqi Geological Journal, 30(2), 85-110.
Numan, N. M. S. (2000). Major cretaceous tectonic events in Iraq. Rafidain Journal of Science, 11(3), 32-54.
Nunez-Betelu, L. & Baceta, J. I. (1994). Basics and Application of Rock- Eval/TOC Pyrolysis: An Example from the Uppermost. Western Pyrenees: Paleocene/lowermost Eocene in The Basque Basin. pp. 5-13.
Othman, R. S. (1990). Generation, Migration and Maturation of the Hydrocarbons in Northern Iraq (Upper Jurassic-Lower Cretaceous). M.S. Thesis (Unpublished), Science College, University of Salahaddin, Erbil, Iraq. p. 208.
Peters, K. E. (1986). Guidelines for evaluating petroleum source rock using programmed pyrolysis. American Association of Petroleum Geologists Bulletin, 70, 318-329.
Peters, K. E. & Moldowan, J. M. (1991). Effects of source, thermal maturity, and biodegradation on the distribution and isomerization of homohopanes in petroleum. Organic Geochemistry, 17(1), 47- 61.
Peters, K. E. & Moldowan, J. M. (1993). The Biomarker Guide- Interpreting Molecular Fossils in Petroleum and Ancient Sediments. New Jersey: Prentice-Hall, Englewood Cliffs. p. 363.
Peters, K. E. & Cassa, M. R. (1994). Applied Source Rock Geochemistry, Chapter 5. In: Magoon, L.B. & Dow, W. G., editors. The Petroleum System—from Source to Trap. Vol. 60. Tulsa: AAPG Memoir. pp. 93-120.
Peters, K. E., Walters, C. C. & Moldowan, J. M. (2005). The Biomarker Guide. Biomarkers and Isotopes in Petroleum Systems and Earth History. 2nd ed., Vol. II. United Kingdom: Cambridge University Press. p. 679.
Pitman, J. K., Steinshour, D. & Lewan, M. D. (2004). Petroleum generation and migration in the Mesopotamian basin and Zagros Fold Belt of Iraq, result from a basin modeling study. GeoArabia, 9(4), 41-72.
Powell, T. G. & McKirdy, D. M. (1973). Relationship between ratio of pristane to phytane, crude oil composition and geological environment. Nature, 243, 37-39.
Rullkötter, J. (1987). Geochemistry, organic. Encyclopedia of Physical Science and Technology, 6, 54-77.
Fatah, S. S. & Mohialdeen, I. M. J. (2016). Hydrocarbon Generation Potential and Thermal Maturity of Middle Jurassic Sargelu Formation in Miran Field. Sulaimani Area, Kurdistan Region, NE Iraq: JZS Special Issue, GeoKurdistan II. pp. 213-228.
Seifert, W. K. & Moldowan, J. M. (1979), The effect of thermal stress on source-rock quality as measured by hopane stereochemistry. Physics and Chemistry of the Earth, 12, 229-237.
Sissakian, V. K. & Al-Jiburi, B. A. M. (2014). Stratigraphy of the high folded zone, Iraqi. Bulletion Geological Minimum Special Issue, 6, 73-161.
Tissot, B. P. & Welte, D. H. (1984). Petroleum Formation and Occurrence. 2nd ed. Berlin: Springer-Verlag. p. 699.
Waples, D. W. & Machihara, T. (1991). Biomarkers for geologists–a practical guide to the application of steranes and triterpanes in petroleum geology. AAPG Methods in Exploration, 9, 91.
Volkman, J. K. (1986). A review of sterol biomarkers for marine and terrigenous organic matter. Organic Geochemistry, 9, 83-99.
Whelan, J. K. & Thompson-Rizer, C.L. (1993). Chemical methods for assessing kerogen and protokerogen types and maturity, Chapter 14, In: Engel, M. H. & Macko, S.A., editors. Principles and Applications: Organic Geochemistry. New York: Plenum Press. pp. 289-353.
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